QUROPE Quantum Information Processing and Communication in Europe

Computational models are an essential tool for the design, characterization, and discovery of novel materials. Hard computational tasks in materials science stretch the limits of existing high-performance supercomputing centers, consuming much of their simulation, analysis, and data resources. Quantum computing, on the other hand, is an emerging technology with the potential to accelerate many of the computational tasks needed for materials science. In order to do that, the quantum technology must interact with conventional high-performance computing in several ways: approximate results validation, identification of hard problems, and synergies in quantum-centric supercomputing. In this paper, we provide a perspective on how quantum-centric supercomputing can help address critical computational problems in materials science, the challenges to face in order to solve representative use cases, and new suggested directions.

Encoding information redundantly using quantum error-correcting (QEC) codes allows one to overcome the inherent sensitivity to noise in quantum computers to ultimately achieve large-scale quantum computation. The Steane QEC method involves preparing an auxiliary logical qubit of the same QEC code used for the data register. The data and auxiliary registers are then coupled with a logical CNOT gate, enabling a measurement of the auxiliary register to reveal the error syndrome. This study presents the implementation of multiple rounds of fault-tolerant Steane QEC on a trapped-ion quantum computer. Various QEC codes are employed, and the results are compared to a previous experimental approach utilizing flag qubits. Our experimental findings show improved logical fidelities for Steane QEC. This establishes experimental Steane QEC as a competitive paradigm for fault-tolerant quantum computing.

Uncertainty relations and quantum entanglement are pivotal concepts in quantum theory. Beyond their fundamental significance in shaping our understanding of the quantum world, they also underpin crucial applications in quantum information theory. In this article, we investigate entropic uncertainty relations and entanglement detection with an emphasis on quantum measurements with design structures. On the one hand, we derive improved R\'enyi entropic uncertainty relations for design-structured measurements, exploiting the property that the sum of powered (e.g., squared) probabilities of obtaining different measurement outcomes is now invariant under unitary transformations of the measured system and can be easily computed. On the other hand, the above property essentially imposes a state-independent upper bound, which is achieved at all pure states, on one's ability to predict local outcomes when performing a set of design-structured measurements on quantum systems. Realizing this, we also obtain criteria for detecting multi-partite entanglement with design-structured measurements.

A quantum algorithm for solving the advection equation based on sparse Hamiltonian simulation is presented. The matrix arising from the finite difference discretisation with explicit Euler time integration is embedded within the Hamiltonian to advance the solution in time. The unitary operator embeds the matrix to a high accuracy regardless of the Hamiltonian evolution time, so a time step succeeds with a high probability and errors of the same order as the conventional Euler method. If postselection does fail, the enacted operation is close to the identity matrix, having a negligible impact on the quantum state and allowing the computation to continue. Qubit requirements grow logarithmically with the number of grid points $N$ and gate requirements grow polynomially as $\widetilde{O}(N^{1/D}Dk/\epsilon)$ (suppressing polylogarithmic terms) in $D$ dimensions with $k$-order spatial discretisation and allowable error $\epsilon$, yielding a significant polynomial speedup over the classical $O(N^{(1+D)/D})$. Statevector simulations of a scalar transported in a two-dimensional laminar channel flow with a combination of periodic and Dirichlet boundary conditions are presented as a proof of concept of the proposed approach.

We characterize the spectrum of the transition matrix for simple random walk on graphs consisting of a finite graph with a finite number of infinite Cayley trees attached. We show that there is a continuous spectrum identical to that for a Cayley tree and, in general, a non-empty pure point spectrum. We apply our results to studying continuous time quantum walk on these graphs. If the pure point spectrum is nonempty the walk is in general confined with a nonzero probability.

Dissipative phase transitions are characteristic features in open quantum systems. Key signatures are the dynamical switching between different states in the vicinity of the phase transition and the appearance of hysteresis. Here, we experimentally study dynamic sweeps across a first order dissipative phase transition in a multi-mode driven-dissipative system. In contrast to previous studies, we perform sweeps of the dissipation strength instead of the driving strength. We extract exponents for the scaling of the hysteresis area in dependence of the sweep time and study the $g^{(2)}(0)$ correlations, which show non-trivial behavior. Due to the multi-mode nature of the system, we can also study the influence of the temperature on the hysteresis area. We compare our results to numerical calculations done for a single mode variant of the system, and find surprisingly good agreement. Furthermore, we identify and discuss the differences between a scan of the dissipation strength and a scan of the driving strength.

Quantum-enhanced auxiliary field quantum Monte Carlo (QC-AFQMC) uses output from a quantum computer to increase the accuracy of its classical counterpart. The algorithm requires the estimation of overlaps between walker states and a trial wavefunction prepared on the quantum computer. We study the applicability of this algorithm in terms of the number of measurements required from the quantum computer and the classical costs of post-processing those measurements. We compare the classical post-processing costs of state-of-the-art measurement schemes using classical shadows to determine the overlaps and argue that the overall post-processing cost stemming from overlap estimations scales like $\mathcal{O}(N^9)$ per walker throughout the algorithm. With further numerical simulations, we compare the variance behavior of the classical shadows when randomizing over different ensembles, e.g., Cliffords and (particle-number restricted) matchgates beyond their respective bounds, and uncover the existence of covariances between overlap estimations of the AFQMC walkers at different imaginary time steps. Moreover, we include analyses of how the error in the overlap estimation propagates into the AFQMC energy and discuss its scaling when increasing the system size.

A transmission line coupled to an externally driven superconducting quantum interference device (SQUID) can exhibit the Dynamical Casimir Effect (DCE). Employing this setup, we quantize the SQUID degrees of freedom and show that it gives rise to a three-body interaction Hamiltonian with the cavity modes. By considering only two interacting modes from the cavities we show that the device can function as an autonomous cooler where the SQUID can be used as a work source to cool down the cavity modes. Moreover, this setup allows for coupling to all modes existing inside the cavities, and we show that by adding two other extra modes to the interaction with the SQUID the cooling effect can be enhanced.

The time evolution of quantum Fisher information, quantum coherence, and non-Markovianity of a V-type three-level atom embedded in free space or a photonic band gap crystal have been investigated. It has been demonstrated that the photonic band gap crystal, as a structured environment, significantly influences the preservation and enhancement of these quantum features. Additionally, we observe that by manipulating the initial relative phase values encoded in the atomic state and the relative positions of the upper levels within the forbidden gap, control over the dynamics of quantum features can be achieved. These findings highlight the potential benefits of utilizing photonic band gap crystals in quantum systems, offering improved preservation and manipulation of quantum information. The ability to control quantum features opens new avenues for applications in quantum information processing and related technologies.

Quantum simulations provide means to probe challenging problems within controllable quantum systems. However, implementing or simulating deep-strong nonlinear couplings between bosonic oscillators on physical platforms remains a challenge. We present a deterministic simulation technique that efficiently and accurately models nonlinear bosonic dynamics. This technique alternates between tunable Rabi and SNAP gates, both of which are available on experimental platforms such as trapped ions and superconducting circuits. Our proposed simulation method facilitates high-fidelity modeling of phenomena that emerge from higher-order bosonic interactions, with an exponential reduction in resource usage compared to other techniques. We demonstrate the potential of our technique by accurately reproducing key phenomena and other distinctive characteristics of ideal nonlinear optomechanical systems. Our technique serves as a valuable tool for simulating complex quantum interactions, simultaneously paving the way for new capabilities in quantum computing through the use of hybrid qubit-oscillator systems.

The synthesis of single-qudit unitaries has mainly been understudied, resulting in inflexible and non-optimal analytical solutions, as well as inefficient and impractical numerical solutions. To address this challenge, we introduce QSweep, a guided numerical synthesizer that produces pulse-optimal single-qudit decompositions for any subspace gateset, outperforming all prior solutions. When decomposing ququart gates, QSweep created circuits 4100x (up to 23500x) faster than QSearch with an average of 7.9 fewer pulses than analytical solutions, resulting in an overall 1.54x and 2.36x improvement in experimental single-qutrit and ququart gate fidelity as measured by randomized benchmarking.

Feasibility of accurate quantum calculations is often restricted by the dimensionality of the truncated Hilbert space required for the numerical computations. The present work demonstrates Bayesian machine learning (ML) models that use quantum properties in an effectively lower-dimensional Hilbert space to make predictions for the Hamiltonian parameters that require a larger basis set as applied to a classical problem in quantum statistical mechanics, the polaron problem. We consider two polaron models: the Su-Schrieffer-Heeger (SSH) model and the mixed SSH-Holstein model. We demonstrate ML models that can extrapolate polaron properties in the phonon frequency. We consider the sharp transition in the ground-state momentum of the SSH polaron and examine the evolution of this transition from the anti-adiabatic regime to the adiabatic regime. We also demonstrate Bayesian models that use the posterior distributions of highly approximate quantum calculations as the prior distribution for models of more accurate quantum results. This drastically reduces the number of fully converged quantum calculations required to map out the polaron dispersion relations for the full range of Hamiltonian parameters of interest.

In this paper we provide an overview of the programmed instructions approach for the purpose of quantum software education. The article presents the programmed instructions method and recent successes in STEM fields before describing its operating mode. Elements tackled include the core components of programmed instructions, its behavioural roots and early use as well as adaptation to complex STEM material. In addition, we offer recommendations for its use in the specific context of quantum software education and provide one example of PI-based instruction for the notion of entanglement. The aim of this work is to provide high-level guidelines for incorporating programmed instructions in quantum education with the goal of disseminating quantum skills and notions more efficiently to a wider audience.

We develop photoelectron interferometry based on laser-assisted extreme ultraviolet ionization for flexible and robust control of photoelectron circular dichroism in randomly oriented chiral molecules. A comb of XUV photons ionizes a sample of chiral molecules in the presence of a time-delayed infrared or visible laser pulse promoting interferences between components of the XUV-ionized photoelectron wave packet. In striking contrast to multicolor phase control schemes relying on pulse shaping techniques, the magnitude of the resulting chiral signal is here controlled by the time delay between the XUV and laser pulses. Furthermore, we show that the relative polarization configurations of the XUV and IR fields allows for disentangling the contributions of bound and continuum states to the chiral response. Our proposal provides a simple, robust and versatile tool for the control of photoelectron circular dichroism and experimentally feasible protocol for probing the individual contributions of bound and continuum states to the PECD in a time-resolved manner.

The study of Maxwell demon and quantum entanglement is important because of its foundational significance in physics and its potential applications in quantum information. Previous research on the Maxwell demon has primarily focused on thermodynamics, taking into account quantum correlations. Here we consider from another perspective and ask whether quantum non-locality correlations can be simulated by performing work. The Maxwell demon-assisted Einstein-Podolsky-Rosen (EPR) steering is thus proposed, which implies a new type of loophole. The application of Landauer's erasure principle suggests that the only way to close this loophole during a steering task is by continuously monitoring the heat fluctuation of the local environment by the participant. We construct a quantum circuit model of Maxwell demon-assisted EPR steering, which can be demonstrated by current programmable quantum processors, such as superconducting quantum computers. Based on this quantum circuit model, we obtain a quantitative formula describing the relationship between energy dissipation due to the work of the demon and quantum non-locality correlation. The result is of great physical interest because it provides a new way to explore and understand the relationship between quantum non-locality, information, and thermodynamics.

We use cluster expansions to establish local indistiguishability of the finite-volume ground states for the AKLT model on decorated hexagonal lattices with decoration parameter at least 5. Our estimates imply that the model satisfies local topological quantum order (LTQO), and so the spectral gap above the ground state is stable against local perturbations.

The widespread success of deep neural networks has revealed a surprise in classical machine learning: very complex models often generalize well while simultaneously overfitting training data. This phenomenon of benign overfitting has been studied for a variety of classical models with the goal of better understanding the mechanisms behind deep learning. Characterizing the phenomenon in the context of quantum machine learning might similarly improve our understanding of the relationship between overfitting, overparameterization, and generalization. In this work, we provide a characterization of benign overfitting in quantum models. To do this, we derive the behavior of a classical interpolating Fourier features models for regression on noisy signals, and show how a class of quantum models exhibits analogous features, thereby linking the structure of quantum circuits (such as data-encoding and state preparation operations) to overparameterization and overfitting in quantum models. We intuitively explain these features according to the ability of the quantum model to interpolate noisy data with locally "spiky" behavior and provide a concrete demonstration example of benign overfitting.

We show that the nearest neighbour entanglement in a mixture of ground and first excited states - a subjacent state - of the J1-J2 Heisenberg quantum spin chain can be used as an order parameter to detect the phase transition of the chain from a gapless spin fluid to a gapped dimer phase. We study the effectiveness of the order parameter for varying relative mixing probabilities between the ground and first excited states in the subjacent state for different system sizes, and extrapolate the results to the thermodynamic limit. We observe that the nearest neighbour concurrence can play a role of a good order parameter even if the system is in the ground state, but with a small finite probability of leaking into the first excited state. Moreover, we apply the order parameter of the subjacent state to investigate the response to separate introductions of anisotropy and of glassy disorder on the phase diagram of the model, and analyse the corresponding finite-size scale exponents and the emergent tricritical point in the former case. The anisotropic J1-J2 chain has a richer phase diagram which is also clearly visible by using the same order parameter.

Quantum superposition of energy eigenstates can appear autonomously in a single quantum two-level system coupled to a low-temperature thermal bath, if such coupling has a proper composite nature. We propose here a principally different and more feasible approach employing engineered interactions between two-level systems being thermalized into a global Gibbs state by weakly coupled thermal bath at temperature $T$. Therefore, in such case quantum coherence appears by a different mechanism, whereas the system-bath coupling does not have to be engineered. We demonstrate such autonomous coherence generation reaching maximum values of coherence. Moreover, it can be alternatively built up by using weaker but collective interaction with several two-level systems. This approach surpasses the coherence generated by the engineered system-bath coupling for comparable interaction strengths and directly reduces phase estimation error in quantum sensing. This represents a necessary step towards the autonomous quantum sensing.

Enantio-conversion of chiral mixtures, converting the mixtures composed of left- and right-handed chiral molecules into the homochiral ensembles, has become an important research topic in chemical and biological fields. In previous studies on enantio-conversion, the tunneling interaction between the left- and right-handed chiral states was often neglected. However, for certain chiral molecules, this tunneling interaction is significant and cannot be ignored. Here we propose a scheme for enantio-conversion of chiral mixtures through optical pumping based on a four-level model of chiral molecules, comprising two chiral ground states and two achiral excited states, with a tunneling interaction between the chiral states. Under one-photon large detuning and two-photon resonance conditions, one of the achiral excited states is eliminated adiabatically. By well designing the detuning and coupling strengths of the electromagnetic fields, the tunneling interaction between two chiral states and the interaction between one of the chiral states and the remaining achiral excited state can be eliminated. Consequently, one chiral state remains unchanged, while the other can be excited to an achiral excited state, establishing chiral-state-selective excitations. By numerically calculating the populations of two chiral ground states and the enantiomeric excess, we observe that high-efficiency enantio-conversion is achieved under the combined effects of system dissipation and chiral-state-selective excitations.